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Hydroboration and Organic Synthesis
9-Borabicyclo [3.3.1] nonane (9-BBN)
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Main description:

9-Borabicyclo [3.3.1]nonane, a commercially available reagent, is the most versatile hydroborating reagent to synthesize organoboranes (B-R-9-BBN). The reagent exhibits remarkable regio-, chemo-, and stereoselectivity during hydroboration reactions. The organoboranes can be converted to C-H, C-O, C-N, C-S, C-halogen, C-metal and above all C-C bonds. In addition, the suitable substituted / unsaturated R of B-R-9-BBN can be utilized to produce dienes, enynes, allenes etc. with defined stereochemistry. 9-BBN’s derivatives have been elegantly used for the asymmetric reduction of ketone moiety. Diels-Alder and Suzuki reactions have expanded the utility of 9-BBN for the synthesis of a variety of organic compounds required for industry. Consequently, this vast field in the form of a book will be helpful to synthetic organic chemists for easy access to literature, required for chemical transformations.


Feature:

Contents is essential for synthetic chemists' everyday life


No systematic compilation of the vast data is available to synthetic chemist


This book will fill the gap


Contents:

Introduction General Remarks Preparations and Properties Kinetic Studies Hydroboration Synthesis of Alcohols Synthesis of Aldehydes and Ketones Synthesis of Carboxylic Acids Synthesis of Esters Synthesis of Nitriles Synthesis of (E) -b ,g - Unsaturated amides Synthesis of Amines Synthesis of Halides Synthesis of Dialkylsulfides Synthesis of Thiophene oligomeres Synthesis of Cyclopropanes and Cyclobutanes Synthesis of Borinanes Synthesis and Transformation of Butterflyboranes Synthesis of a - Bromoboranes Synthesis of Borinates Synthesis and Transformation of Polymers Synthesis of alkali metal 9- boratabicyclo [3.3.1] nonane Synthesis of B – R – 9 – BBN not available via hydroboration Synthesis of unsaturated compounds Reduction AsymmetricReduction Cleavage of Ethers Trans – Metalation Separations of isomers Diels - Alder reaction Suzuki Reaction Miscellaneous


PRODUCT DETAILS

ISBN-13: 9783642080340
Publisher: Springer (Springer Berlin Heidelberg)
Publication date: October, 2010
Pages: 586
Weight: 908g
Availability: POD
Subcategories: Biochemistry

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